GLIDDEN CO -- INTERIOR SEMI-GLOSS, 9082 -- 8010-00N077226
===================== Product Identification ===================== Product ID:INTERIOR SEMI-GLOSS, 9082 MSDS Date:07/05/1995 FSC:8010 NIIN:00N077226 === Responsible Party === Company Name:GLIDDEN CO Address:925 EUCLID AVE City:CLEVELAND State:OH ZIP:44115 Country:US Info Phone Num:216-344-8207 Emergency Phone Num:800-545-2643 CAGE:72818 === Contractor Identification === Company Name:GLIDDEN CO MEMBER OF ICI WORLD PAINTS Address:925 EUCLID AVE Box:15049 City:CLEVELAND State:OH ZIP:44115 Country:US Phone:216-344-8000 CAGE:72818 Company Name:GLIDDEN PAINT, ICI PAINTS NORTH AMERICA Address:925 EUCLID AVE Box:City:CLEVELAND State:OH ZIP:44115 Country:US Phone:800-545-2643/216-344-8207 CAGE:01PD6 ============= Composition/Information on Ingredients ============= Ingred Name:ACETIC ACID, VINYL ESTER, (ACETIC ACID, ETHENYL ESTER); (VINYL ACETATE) (SARA 302/313) (CERCLA) CAS:108-05-4 RTECS #:AK0875000 Fraction by Wt: 0.1-1.0% OSHA PEL:10 PPM ACGIH TLV:10 PPM/15, A3 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CLAY (KAOLIN); (KAOLIN) CAS:1332-58-7 RTECS #:GF1670500 Fraction by Wt: 5-10% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:2 MG/M3 TDUST Ingred Name:PROPIONIC ACID, 2-METHYL-, MONOESTER WITH 2,2,4-TRIMETHYL-1,3-PENTANEDIOL CAS:25265-77-4 RTECS #:UF6000000 Fraction by Wt: 1-5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 10-20% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:VINYL ACETATE POLYMER; (BUTYL ACRYLATE-VINYL ACETATE POLYMER) CAS:25067-01-0 Fraction by Wt: 10-20% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 10-20% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 40-50% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:EFTS OF OVEREXP: RESP PROBLEMS, INTOXICATION, ANESTH EFT/NARCOS, CNS DMG, BURNS OF MOUTH, THROAT, STOM, LIVER & (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: KIDNEY DMG, BLADDER DMG, PULM EDEMA, LOSS OF CONSCIOUSNESS, CYANOSIS, ACUTE POISONING, RESP FAILURE, (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: CARDIAC FAILURE, BRAIN DAMAGE, DEATH. MAY BE ABSORBED THROUGH THE SKIN. RTECS #:9999999ZZ Ingred Name:SPILL PROC: LGE SPILLS: SHUT OFF LEAK IF SAFE TO DO SO. DIKE & CONTAIN SPILL. PUMP TO STOR/SALVAGE VESSELS. (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: USE ABSORB TO PICK UP EXCESS RESIDUE. KEEP SALVAGEABLE MATL & RINSE WATER OUT OF SEWERS & WATERCOURSES. (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: SMALL SPILLS: USE ABSORBENT TO PICK UP RESIDUE AND DISPOSE OF PROPERLY. RTECS #:9999999ZZ Ingred Name:OTHER PREC: ABRADING (SANDING) PAINTED SURFS. IF SUCH CNDTNS CANNOT BE AVOIDED, USE APPROP RESP PROT AS DIRECTED(ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: UNDER SPECIAL PROT INFO. EMPTY CONTRS MAY CONTAIN HAZ RESIDUES. GROUND EQUIP WHEN TRANSFERRING TO (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: PREVENT ACCUMULATION OF STATIC CHARGE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE/CHRONIC:INHAL:IRRIT OF RESP TRACT, LUNGS. PRLNG INHAL MAY LEAD TO MUC MEMB IRRIT, DROW, DIZZ &/LT HEAD, HDCH, UNCOORD, NAUS, VOMIT, GI DISTURBS, COUGHING, SNEEZING, APATHY, CNS DEPRESS, ANESTH E FT/NARCOS, BLOOD ABNORM, KIDNEY DMG, PNEUMOCONIOSIS, LOSS OF CONSCIOUSNESS. SKIN:IRRIT. PRLNG/RPTD CONT(EFTS OF OVEREXP) Explanation of Carcinogenicity:ACETIC ACID, VINYL ESTER: IARC MONO ON EVALUATION OF CARCIN RISK OF CHEMICALS TO MAN, VOL 63, PG 477, 1995: GROUP 2B. Effects of Overexposure:HLTH HAZ:CAN CAUSE DERM, DEFAT, BLISTERING, SEV IRRIT. POSS SENSIT. MAY RSLT IN DERMAL ABSORPTION, WHICH MAY CAUSE APATHY. EYE:IRRIT. PRLNG/RPTD CONT CAN CAUSE TEARING, REDNESS, SEV IRRIT. INGEST:MAY CAUSE FATG, DROW, DIZZ &/LT HEAD, HDCH,NAUS, VOMIT, DIARR, GI DISTURBS, SEV ABDOM PAIN, APATHY, CNS DEPRESS, (ING 9) Medical Cond Aggravated by Exposure:EYE, SKIN, RESPIRATORY DISRODERS, KIDNEY DISORDERS, LIVER DISORDERS, NERVOUS SYSTEM DISORDERS. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG. GER EMER MED ATTN. HAVE TRAINED PERS GIVE OXYGEN IF NEC. GET MED HELP FOR ANY BRTHG DFCLTY. SKIN:FLUSH FROM SKIN W/WATER, THEN WASH THORO W/SOAP & WATER. REMOVE CONTAM CLTHG & WASH BEFORE REUSE. EYE:FLUSH IMMED W/LGE AMTS OF WATER, ESP UNDER LIDS FOR AT LEAST 15 MIN. IF IRRIT/OTHER EFTS PERSIST, OBTAIN MED TREATMENT. INGEST: (SUP DAT) ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:DRY CHEMICAL, FOAM, WATER FOG, CARBON DIOXIDE. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:CLSD CONTRS MAY EXPLODE/BURST WHEN EXPOSED TO EXTREME HEAT/FIRE. VAPS ARE HVR/AIR & MAY TRAVEL LONG DISTS TO SOURCE OF IGNIT & FLASH BACK. VAPS CAN (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:COMPLY W/ALL APPLIC HLTH & ENVIRON REGS. ELIM ALL SOURCES OF IGNIT. VENT AREA. SPILLS MAY BE COLLECTED W/ABSORB MATLS. EVACUATE ALL UNNEC PERS. PLACE COLLECTED MATL IN PROPER CONTR. COMPLETE PERS PROT EQUIP MUST BE USED DURING CLEANUP. (ING 12) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 100F. KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. KEEP FROM FREEZING. KEEP CONTR TIGHTLY CLSD IN WELL-VENTD AREA. USE ONLY W/ADEQ VENT. Other Precautions:DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID CONT W/SKIN & EYES, & BRTHG OF VAPS. KEEP CONTRS TIGHTLY CLSD & UPRIGHT WHEN NOT IN USE. AVOID CNDTNS WHICH RSLT IN FORM OF INHALABLE PARTI CLES SUCH AS SPRAYING OR (ING 15) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE STANDARDS. WHERE RESPIRATORY PROTECTION IS REQUIRED, USE ONLY NIOSH APPROVED RESPIRATORS IN ACCORDANCE WITH OSHA STANDARD 29 CFR 1910.134. Ventilation:PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT BUILD-UP OF VAPORS. Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . IMPERVIOUS CLOTHING, APRON, BOOTS. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY BEFORE EATING OR SMOKING. Supplemental Safety and Health EXPLO HAZ: FORM EXPLO MIXS IN AIR AT ELEVATED TEMPS. IN CLSD TANKS, WATER/FOAM MAY CAUSE FROTHING/ERUPTION. MATLS TO AVOID: ACID, MAGNESIUM, CAUSTICS, MINERAL ACIDS, SODIUM, POTASSIUM, HEAVY METALS. F IRST AID PROC:OBTAIN MED TREATMENT IMMED. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>163F,>73C Spec Gravity:1.19 VOC Pounds/Gallon:85 Appearance and Odor:ANTIQUE WHITE Percent Volatiles by Volume:71.94 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, ACIDS, REDUCING AGENTS, BASES, ALUMINUM, ZINC, IRON, METALS, PEROXIDES, NITRIC ACID, HYDROFLUORIC (SUP DAT) Stability Condition to Avoid:ELEVATED TEMPS, CONT W/OXIDIZING AGENTS, CONT W/ALUMINUM/ZINC, ULTRAVIOLET LIGHT, FREEZING, SPARKS, OPEN FLAME. Hazardous Decomposition Products:CARBON MONOXIDE & DIOXIDE, ACRID FUMES, OXIDES OF PHOSPHORUS, OXYGEN, ALDEHYDES, TOX GASES, ACIDS. PROPIONALDEHYDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS . ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.