UNION OIL CO OF CALIFORNIA UNOCAL CHEMICALS DIV -- DIESEL 2 -- 9140-00-286-5296
===================== Product Identification ===================== Product ID:DIESEL 2 MSDS Date:05/09/1990 FSC:9140 NIIN:00-286-5296 === Responsible Party === Company Name:UNION OIL CO OF CALIFORNIA UNOCAL CHEMICALS DIV Address:1201 W 5TH ST Box:60455 City:LOS ANGELES State:CA ZIP:90060 Country:US Info Phone Num:213-977-7589 Emergency Phone Num:800-424-9300(CHEMTREC)/503-641-3222 CAGE:23034 === Contractor Identification === Company Name:76 PRODUCTS CO Address:1201 W 5TH ST Box:City:LOS ANGELES State:CA ZIP:90017 Country:US Phone:213-977-7589 CAGE:23034 ============= Composition/Information on Ingredients ============= Ingred Name:NAPHTHALENE (SARA III) CAS:91-20-3 RTECS #:QJ0525000 Fraction by Wt: <1% OSHA PEL:10 PPM/15 STEL ACGIH TLV:10 PPM/15 STEL; 9192 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:DIPHENYL (BIPHENYL) (SARA III) CAS:92-52-4 RTECS #:DU8050000 Fraction by Wt: <1% OSHA PEL:0.2 PPM ACGIH TLV:0.2 PPM; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:PETROLEUM MID-DISTILLATE (DIESEL MARINE FUEL) CAS:68476-34-6 Fraction by Wt: > 98% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 AS OIL MIST ACGIH TLV:5 MG/M3 AS OIL MIST ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:THIS MATERIAL HAS A LOW DEGREE OF TOXICITY. HOWEVER, BREATHING OF HIGH CONCENTRATIONS OF VAPORS OR MISTS MAY CAUSE IRRITATION OF THE NOSE, THROAT, AND SIGNS OF NERVOUS SYSTEM DEPRESSION. INGESTION OF EXCESSIVE QUANTITIES MAY CAUSE IRRITATION OF THE DIGENTIVE TRACT ANS SIGNS OF NERVOUS SYSTEM DEPRESSION. Explanation of Carcinogenicity:DIESEL EXHAUST MAY BE A PROBABLE HUMAN CANCER HAZARD, BUT IT HAS NOT BEEN IDENTIFIED BY ANY OF THE ABOVE AGENCIES YET. Effects of Overexposure:EYES, SKIN, RESPIRATORY AND GASTROINTESTINAL TRACT IRRITATION, HEADACHE, DIZZINESS, NAUSEA, VOMITING Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS MATERIAL. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH CLEAN WATER; SKIN: REMOVE CONTAMINATED CLOTHING. IF SKIN SURFACE IS DAMAGED, SEEK MEDICAL HELP, IF NOT DAMAGED, WASH WITH MILD SOAP & WATER; INHALE: REMOVE TO FRESH AIR. IF NOT BREATHI NG, APPLY ARTIFICIAL RESPIRATION. USE OXYGEN IF NEEDED, BUT BY QUALIFIED PERSONNEL ONLY; INGEST: DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:140F,60C Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR HALON. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. AVOID SPREADING BURNING LIQUID WITH WATER USED FOR COOLING PURPOSE. Unusual Fire/Explosion Hazard:THIS MATERIAL IS COMBUSTIBLE AND MAY BE IGNITED BY HEAT, SPARKS, FLAME, OR OTHER SOURCES OF IGNITION. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP ALL SOURCES OF IGNITION AWAY FROM SPILL/ELEASE. STAY UPWIND AND AWAY FROM IT. ISOLATE HAZARD AREA & LIMIT ENTRY TO AUTHORIZED PERSONNEL.STOP LEAK IF IT CAN BE DONE WITHOUT RISK. WEAR PROTECTIVE C LOTHING. AVOID SPILL ENTERING INTO ANY WATERWORKS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED. STORE IN COOL, DRY, WELL VENTILATED AREAS AWAY FROM HEAT AND ALL SOURCES OF IGNITIONS. Other Precautions:STORE ONLY IN APPROVED CONTAINERS. KEEP AWAY FROM ANY INCOMPATIBLE MATERIALS. PROTECT CONTAINERS AGAINST ANY PHYSICAL DAMAGES. THE USE OF EXPLOSION-PROOF EQUIPMENT IS RECOMMENDED AND MAY BE REQUIRED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DEPENDING ON THE AIRBORNE CONCENTRATION, USE A RESPIRATOR OR GAS MASK WITH APPROPRIATE CARTRIDGES AND CANNISTERS OR SUPPLIED EQUIPMENT. Ventilation:USE ADEQUATE VENTILATION TO KEEP BELOW TLV. Protective Gloves:IMPERMEABLE GLOVES. Eye Protection:SAFETY GOGGLES. Other Protective Equipment:A SOURCE OF CLEAN WATER BE AVAILABLE IN THE WORK AREA FOR FLUSHING EYES AND SKIN. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F4 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:490F,254C Vapor Density:>1 Spec Gravity:0.85 Evaporation Rate & Reference:<1 (BUTYL ACETATE =1) Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR TO YELLOW LIQUID WITH CHARACTERISTIC PETROLEUM ODOR Percent Volatiles by Volume:98 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:OXIDES OF CARBON AND SMALL AMOUNTS OF OXIDES OF SULFUR AND NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF PRODUCT IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. 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